Summary
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1.
The high activity of fresh silicon-copper alloy for the dehydrochlorination of ethyl chloride was made use of for the purpose of raising the yield of dichlorpethylsilane in the reaction between a silicon-copper alloy and ethyl
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2.
On the basis of the relationships found, a method is proposed for raising the yield of dichloroethylsilane in the continuous synthesis of chloroethylsilanes.
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Literature cited
K. A. Andrianov, R. A. Turetskaya, S. A. Golubtsov, and I. V. Trofimova, Izv. AN SSSR, Otd. khim. n.1962, 1788.
Chemistry and Practical Application of Organosilicon Compounds [in Russian]. Transactions of a Conference. No. 6, Izd. AN SSSR, 1961, p. 26.
K. A. Andrianov, S. A. Golubtsov, I. V. Trofimova, A. S. Denisova, and R. A. Turetskaya, Dokl. AN SSSR108 3, 465 (1956.
R. A. Turetskaya, S. A. Golubtsov, I. V. Trofimova, and K. A. Andrianov, Khim. prom., 1963 (in press).
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Golubtsov, S.A., Turetskaya, R.A., Andrianov, K.A. et al. Formation of alkyl(or aryl)chlorosilanes by the direct reaction of alkyl(or aryl)chlorides with silicon communication 3. Direct synthesis of dichloroethylsilane. Russ Chem Bull 12, 77–80 (1963). https://doi.org/10.1007/BF00846953
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DOI: https://doi.org/10.1007/BF00846953