Summary
The peculiar features of Nieuwland's reaction between p-diethynylbenzene and ketones were determined. It leads primarily to the formation of monohydric alcohols. By reduction in the proportion of p-diethynylbenzene, the reaction can be directed toward increased yield of the diols.
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Fisher, L.B., Kotlyarevskii, I.L. Highly unsaturated polymers Communication 11. Mono-and di-hydric alcohols derived from p-diethynylbenzene. Russ Chem Bull 14, 667–672 (1965). https://doi.org/10.1007/BF00846725
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DOI: https://doi.org/10.1007/BF00846725