Summary
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1.
A method was developed for the synthesis of α,β,β'-trialkyl-substituted cyclopentadienes fromγ-diketones, which were obtained from furan compounds.
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2.
It was shown that it is possible to go from compounds of the furan series to trialkylcyclopentadienes.
Literature cited
N. I. Shuikin and T. I. Naryshkina, Izv. AN SSSR, Otd. Khim. Nauk,1958, 316;1958, 508; Neftekhimiya, No. 1, 44 (1962).
N. I. Shuikin and T. I. Naryshkina, Neftekhimiya, No. 4, 473 (1962); No. 6, 859 (1963).
H. Hunsdiecker, Ber.,75, 447 (1942).
I. F. Bel'skii and R. A. Karakhanov, Izv. AN SSSR, Otd. Khim. Nauk,1962, 907.
V. A. Mironov, S. N. Kostina, E. V. Sobolev, and A. N. Elizarova, Izv. AN SSSR, Ser. Khim.,1964, 864.
N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR,131, 109 (1960).
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The spectra were taken by E. V. Sobolev, for which the authors wish to express their sincere thanks.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 570–571, March, 1965
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Naryshkina, T.I., Bel'skii, I.F. Synthesis of cyclopentadiene homologs. Russ Chem Bull 14, 557–558 (1965). https://doi.org/10.1007/BF00846630
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DOI: https://doi.org/10.1007/BF00846630