Summary
-
1.
Water is a necessary reagent for the oxidation reaction when cellulose is reacted with nitrogen oxides.
-
2.
Carboxylcellulose dinitrate was obtained, having a COOH group attached to C6 and O-NO2 groups attached to C2 and C3 of the anhydroglucose unit.
-
3.
The nitration of cellulose with gaseous nitrogen oxides was accomplished.
Literature cited
P. P. Shorygin and É. V. Khait, Zh. Obshch. Khimii,7, 188 (1937).
C. Unruh and W. Kenyon, J. Amer. Chem. Soc.,64, 127 (1942).
E. Vackel and W. Kenyon, J. Amer. Chem. Soc.,64, 121 (1942).
K. Mauer and G. Reiff, J. Makromol. Chem.,1, 27 (1943).
P. A. McGee, W. F. Fowler, Jr., E. W. Taylor, C. C. Unruh, and W. O. Kenyon, J. Amer. Chem. Soc.,69, 355 (1947).
E. D. Kaverzneva, Dokl. AN SSSR,68, 865 (1949).
T. P. Nevell, J. Text. Inst.,42, No. 3, T91; No. 3, T130 (1951).
E. D. Kaverzneva, V. I. Ivanov, A. S. Salova, and S. A. Kist, Izv. AN SSSR, Otd. Khim. Nauk,1956, 358.
G. M. Nabar, F. Scholefield, and H. A. Turner, J. Soc. Dyers and Colourists,53, 5 (1937).
E. D. Kaverzneva, Izv. AN SSSR, Otd. Khim. Nauk,1959, 344.
Yu. A. Zverev, Dissertation [in Russian], (Leningrad, 1954).
Z. A. Rogovin, L. M. Kondrashuk, and R. A. Malakhov, Zh. Priklad. Khimii,23, 418 (1950).
I. N. Ermolenko, Spectroscopy in the Chemistry of Oxidized Celluloses [in Russian], p. 248, Izd. AN BSSR, (Minsk, 1959).
W. W. Pigman, B. L. Browning, W. H. McPherson, E. R. Calkins, and R. L. Leaf, Jr., J. Amer. Chem. Soc.,71, 2200 (1949).
E. D. Kaverzneva, V. I. Ivanov, and A. S. Salova, Izv. AN SSSR, Otd. Khim. Nauk,1956, 482.
L. Pinck, Industr. and Engng. Chem.,22, 1241 (1930).
I. Clark and M. Millet, Tappi,44, 144 (1961).
F. Seel, G. Fuchs, and D. Werner, Ber.96, 179 (1963).
E. K. Gladding and C. B. Purves, Paper Trade J.,116, No. 14, 26 (1943).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 557–559, March, 1965
Rights and permissions
About this article
Cite this article
Kuznetsova, Z.I., Ivanova, V.S. & Shorygina, N.N. Some new data on the reaction of cellulose with gaseous nitrogen oxides. Russ Chem Bull 14, 540–542 (1965). https://doi.org/10.1007/BF00846625
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00846625