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Reaction of organolithium compounds of p-bromodiphenyl and p-bromo(chloro) diphenylmethane with dimethyldichlorosilane and dimethyldichlorogermane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We were the first to obtain and characterize di(biphenyl)dimethylgermane.

  2. 2.

    When p-C6H5CH2C6H4Li is reacted with (CH3)2GeCl2, (CH3)2SiCl2 or CO2 one of the reaction products is 1,1,2,2-tetraphenylethane. Its formation indicates the possible autometalation of p-benzylphenyllithium to diphenylmethyllithium.

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Literature cited

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Authors and Affiliations

  1. N. D. Zeinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    A. D. Petrov, M. A. Chel'tsova & S. D. Komarova

Authors
  1. A. D. Petrov
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  2. M. A. Chel'tsova
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  3. S. D. Komarova
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 550–552, March, 1965

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Petrov, A.D., Chel'tsova, M.A. & Komarova, S.D. Reaction of organolithium compounds of p-bromodiphenyl and p-bromo(chloro) diphenylmethane with dimethyldichlorosilane and dimethyldichlorogermane. Russ Chem Bull 14, 531–533 (1965). https://doi.org/10.1007/BF00846622

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  • DOI: https://doi.org/10.1007/BF00846622

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