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Comparative study of different methods for the preparation of dichlorocarbene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A comparative study of the different methods for obtaining dichlorocarbene was made by the method of “competing” addition.

  2. 2.

    The relative rate constants for the dichloromethylenation of cyclohexene and a number of its 1-substituted derivatives were determined, and also their relative reactivity in this reaction, which values are found to be in complete agreement with the electronic nature of the substituents attached to the multiple bond, and are independent of the method used to generate the dichlorocarbene.

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Authors and Affiliations

  1. N. S. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    O. M. Nefedov & R. N. Shafran

Authors
  1. O. M. Nefedov
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  2. R. N. Shafran
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 538–541, March, 1965

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Nefedov, O.M., Shafran, R.N. Comparative study of different methods for the preparation of dichlorocarbene. Russ Chem Bull 14, 515–518 (1965). https://doi.org/10.1007/BF00846617

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  • DOI: https://doi.org/10.1007/BF00846617

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