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Synthesis of oligomeric polymethylenephosphonic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The oxidative chlorophosphonation of a solid paraffin was studied. By employing high oxygen passage rates it is possible to introduce up to 29% phosphorus into the polymethylene chain and obtain an oligomer, in which, on the average, one phosphonyl group is present for each two methylene groups.

  2. 2.

    Some of the properties of the obtained polymethylenephosphonic acids were studied.

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Literature cited

  1. L. Z. Soborovskii, Yu. M. Zinov'ev, and M. A. Énglin Dokl. AN SSSR,67, 293 (1949); Avt. Svid. [a form of Russian patent] No. 117,901; Byull. Izobr., No. 3, 14 (1959).

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  2. J. O. Clayton and W. L. Jensen, J. Am. Chem. Soc.,70, 3880 (1948); Brit. Patent 648,328; Chem. Abstrs45, 71361 (1951).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR

    S. R. Rafikov, M. E. Ergebekov, G. N. Chelnokova & T. V. Ershova

  2. Institute of Chemical Sciences of the Academy of Sciences of the KazakhSSR, USSR

    S. R. Rafikov, M. E. Ergebekov, G. N. Chelnokova & T. V. Ershova

Authors
  1. S. R. Rafikov
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  2. M. E. Ergebekov
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  3. G. N. Chelnokova
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  4. T. V. Ershova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 526–527, March, 1965

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Rafikov, S.R., Ergebekov, M.E., Chelnokova, G.N. et al. Synthesis of oligomeric polymethylenephosphonic acids. Russ Chem Bull 14, 500–501 (1965). https://doi.org/10.1007/BF00846611

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  • DOI: https://doi.org/10.1007/BF00846611

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