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Steric relations in diene condensations of cyclopentadiene with monosubstituted ethylenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reactions of cyclopentadiene with vinyl chloride and with vinyl acetate give, in the first place, the kinetically favored endo adducts, which are then converted into their thermodynamically stable isomers.

  2. 2.

    For vinyl chloride the exo adduct is the stable form.

  3. 3.

    11-Bromo-9,10-dihydro-9,10-ethanoanthracene, 9,10-dihydro-9,10-ethanoanthracen-11-ol, and the cyclopentadiene diadduct of vinyl bromide were synthesized.

  4. 4.

    The dipole moments of the compounds synthesized and of some previously described compounds were measured.

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Authors and Affiliations

  1. V. I. Ul'yanov -Lenin Kazan' State University, USSR

    B. A. Arbuzov & A. N. Vereshchagin

Authors
  1. B. A. Arbuzov
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  2. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 401–408, March, 1965

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 486–491, March, 1965

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Arbuzov, B.A., Vereshchagin, A.N. Steric relations in diene condensations of cyclopentadiene with monosubstituted ethylenes. Russ Chem Bull 14, 466–470 (1965). https://doi.org/10.1007/BF00846604

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  • DOI: https://doi.org/10.1007/BF00846604

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