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Reactions of carbon tetrachloride with unsaturated compounds in presence of dicyclohexyl peroxydicarbonate or oxidation-reduction systems

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The oxidation-reduction system benzoyl peroxide-dimethylaniline initiates the addition of carbon tetrachloride to alkyl vinyl ethers and the telomerization of allyl acetate with carbon tetrachloride at 25–30dg.

  2. 2.

    The oxidation-reduction system benzoyl peroxide-(p-tolylsulfonyl)methanol-iron triacetylacetonate initiates the telomerization of allyl acetate with carbon tetrachloride at 30–32dg.

  3. 3.

    Dicyclohexyl peroxydicarbonate initiates the addition of carbon tetrachloride to butyl vinyl ether at 30° and the telomerization of allyl acetate, allyl chloride, and 1-octene with carbon tetrachloride at 55–60dg.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    E. Ts. Chukovskaya, A. A. Kamyshova & R. Kh. Freidlina

Authors
  1. E. Ts. Chukovskaya
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  2. A. A. Kamyshova
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  3. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 461–465, March, 1965

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Chukovskaya, E.T., Kamyshova, A.A. & Freidlina, R.K. Reactions of carbon tetrachloride with unsaturated compounds in presence of dicyclohexyl peroxydicarbonate or oxidation-reduction systems. Russ Chem Bull 14, 445–449 (1965). https://doi.org/10.1007/BF00846601

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  • DOI: https://doi.org/10.1007/BF00846601

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