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Summary

  1. 1.

    With amino compounds hexafluoroacetone forms relatively stable gemical amino alcohols, which do not undergo dehydration.

  2. 2.

    A number of special methods were developed for the preparation of hexafluoroacetone imines; these were based on the decomposition of hexafluoro-2,2-propanediamine derivatives.

  3. 3.

    Trifluoroacetaldehyde, 1,1,1-trifluoroacetone, and pentafluoronitroacetone imines were prepared by Staudinger's reaction, and a number of their reactions were studied.

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Literature cited

  1. H. P. Braendlin and E. T. McBee, “Advances in Fluorine Chemistry,” (London, 1963), p. 1.

  2. W. R. Nes and A. Burger, J. Amer. Chem. Soc.,72, 5410 (1950).

    Google Scholar 

  3. M. Hauptstein and R. A. Braun, J. Amer. Chem. Soc.,77, 4930 (1955).

    Google Scholar 

  4. I. L. Knunyants and A. V. Fokin, Izv. AN SSSR. Ser. khim., in the press.

  5. I. L. Knunyants, Ch'en Ch'ing-yün, N. P. Gambaryan, and E. M. Rokhlin, Zh. VKhO im. Mendeleeva,5, 114 (1960).

    Google Scholar 

  6. I. L. Knunyants, Ch'en Ch'ing-yün, N. P. Gambaryan, and E. M. Rokhlin, Zh. VKhO im. Mendeleeva, 1962, 684.

  7. I. L. Knunyants, E. M. Rokhlin, N. P. Gambaryan, Yu. A. Cheburkov, and Ch'en Ch'ing-yün, Khim. nauka iprom -st 1,4, 802 (1959).

    Google Scholar 

  8. I. L. Knunyants and N. P. Gambaryan, Izv. AN SSSR. Ser. khim., in the press.

  9. Yu. V. Zeifman, N. P. Gambaryan, and I. L. Knunyants, Dokl. AN SSSR,153, 1334 (1963).

    Google Scholar 

  10. I. L. Knunyants, B. L. Dyatkin, L. S. German, V. A. Komarov, and I. N. Rozhkov, Zh. VKhO im. Mendeleeva,8, 709 (1963).

    Google Scholar 

  11. H. Staudinger and E. Hauser, Helv. chim. acta,4, 874 (1921).

    Google Scholar 

  12. R. Albrecht, G. Kresze, and B. Mlakar, Chem. Ber.,97, 483 (1964).

    Google Scholar 

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This article is published in accordance with a resolution of the Conference of Chief Editors of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by Yu. V. Zeifman.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 450–456, March, 1965

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Zeifman, Y.V., Gambaryan, N.P. & Knunyants, I.L. Perfluoro ketone imines. Russ Chem Bull 14, 435–441 (1965). https://doi.org/10.1007/BF00846599

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  • DOI: https://doi.org/10.1007/BF00846599

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