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Constants of chain transfer in the telomerization of ethylene with chloroform

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The particular and general chain transfer constants were measured in the reaction of telomerization of ethylene by chloroform, and the influence of temperature on the conversion constants of the telomer radicals in this reaction was studied.

  2. 2.

    Conducting the telomerization of ethylene with carbon tetrachloride and chloroform without mixing or under heterogeneous conditions leads to a substantial increase in the chain transfer constants.

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Literature cited

  1. I. B. Afanas'ev and A. A. Beé r, Neftekhimiya,2, 611 (1962).

    Google Scholar 

  2. F. W. Mellows and M. Burton, J. Phys. Chem.66, 2164 (1962).

    Google Scholar 

  3. F. R. Mayo, J. Amer. Chem. Soc.,70, 3689 (1948).

    Google Scholar 

  4. B. A. Énglin and R. Kh. Freidlina, Dokl. AN SSSR,154, 922 (1964).

    Google Scholar 

  5. C. Walling, Free Radicals in Solution [Russian translation], (IL, 1960), p. 205.

  6. C. Walling, Free Radicals in Solution [Russian translation]. (IL, 1960), p. 194.

  7. F. R. Mayo and R. A. Gregg, Disc. Faraday Soc.,2, 328 (1947); J. Amer. Chem. Soc.,75, 3530 (1953).

    Google Scholar 

  8. R. N. Chadha, J. S. Shukla, and G. S. Misra, Trans. Faraday Soc.,53, 240 (1957).

    Google Scholar 

  9. W. V. Smith, J. Amer. Chem. Soc.,68, 2059 (1946).

    Google Scholar 

  10. N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity [in Russian],(Izd. AN SSSR, Moscow, 1958), p. 137.

    Google Scholar 

  11. C. Walling, J. Amer. Chem. Soc.,70, 2561 (1948).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    B. A. Énglin & R. Kh. Freidlina

Authors
  1. B. A. Énglin
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  2. R. Kh. Freidlina
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Additional information

The article is published on the basis of a resolution of the Conference of Editors in Chief of the journals of the Academy of Sciences, USSR of July 12, 1962 as the dissertation work of B. A. Énglin.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 425–431, March, 1965

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Énglin, B.A., Freidlina, R.K. Constants of chain transfer in the telomerization of ethylene with chloroform. Russ Chem Bull 14, 411–417 (1965). https://doi.org/10.1007/BF00846594

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  • DOI: https://doi.org/10.1007/BF00846594

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