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Preparation and isomerization of dialkyl, diaryl, and alkylene 2-(2-chloroethoxy)-1-(chloromethyl)ethyl phosphites

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    On vacuum distillation dialkyl 2-(2-chloroethoxy)-1-(chloromethyl)ethyl phosphites undergo redistribution of phosphorus-attached alkoxyls.

  2. 2.

    When heated, mixed 2-(2-chloroethoxy)-1-(chloromethyl)ethyl phosphites not only undergo the main, isomerization reaction, but also react with elimination of alkyl chloride.

  3. 3.

    The action of acetyl chloride on 2-(2-chloroethoxy)-1-(chloromethyl)ethyl (chloromethyl)ethylene phosphite leads to the formation of (chloromethyl)ethylene phosphorochloridite.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of USSR, Kazan'

    V. K. Khairullin & T. I. Sobchuk

Authors
  1. V. K. Khairullin
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  2. T. I. Sobchuk
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Khairullin, V.K., Sobchuk, T.I. Preparation and isomerization of dialkyl, diaryl, and alkylene 2-(2-chloroethoxy)-1-(chloromethyl)ethyl phosphites. Russ Chem Bull 12, 291–297 (1963). https://doi.org/10.1007/BF00846400

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  • DOI: https://doi.org/10.1007/BF00846400

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