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Polymerization of monoallyl silicon derivatives in presence of the catalyst system (i-C4H9)3Al+TiCl4

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the polymerization of allyltrimethylsilane and of allyldimethylphenylsilane in presence of the complex catalyst (i-C4H9)3 Al+TiCl4, high-molecular crystalline polyallyltrimethylsilane and polyallyldimethylphenylsilane can be obtained.

  2. 2.

    A study was made of the effect of the relative amounts of triisobutylaluminum and titanium tetrachloride on the yield and properties of the solid polymers.

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Literature cited

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Authors and Affiliations

  1. Institute of Petrochemical Synthesis, Academy of Sciences, USSR

    A. V. Topchiev, N. S. Nametkin, Ch'iu Hsiao-p'ei, S. G. Durgar'yan & V. I. Zav'yalov

Authors
  1. A. V. Topchiev
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  2. N. S. Nametkin
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  3. Ch'iu Hsiao-p'ei
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  4. S. G. Durgar'yan
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  5. V. I. Zav'yalov
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Additional information

The authors express their thanks to M. M. Kusakov and V. D. Oppengeim.

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Topchiev, A.V., Nametkin, N.S., Hsiao-p'ei, C. et al. Polymerization of monoallyl silicon derivatives in presence of the catalyst system (i-C4H9)3Al+TiCl4 . Russ Chem Bull 12, 244–249 (1963). https://doi.org/10.1007/BF00846390

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  • DOI: https://doi.org/10.1007/BF00846390

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