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Determination of rate constants for the decay of initiators and initiation efficiency

  • Z. I. Kulitski
  • L. M. Terman
  • V. F. Tsepalov
  • V. Ya. Shlyapintokh
Physical Chemistry

Summary

  1. 1.

    Measurements have been made of the oxidation rates of cumene and ethylbenzene initiated by azo-bis-iso-butyronitrile and dicyclohexylperoxidicarbonate in the temperature range 60–90°, and the initiator decay rate constants have been found.

     
  2. 2.

    In ethylbenzene, the yield of radicals per molecule of azo-bis-isobutyronitrile decomposed is 1.1, and 1.4 per molecule ot dicyclohexylperoxydicarbonate.

     

Keywords

Oxidation Decay Rate Oxidation Rate Ethylbenzene Cumene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau Enterprises, Inc 1963

Authors and Affiliations

  • Z. I. Kulitski
    • 1
  • L. M. Terman
    • 1
  • V. F. Tsepalov
    • 1
  • V. Ya. Shlyapintokh
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of SciencesUSSR

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