β-Dicarbonyl compounds Communication 21. Difference in chemical behavior between 2-methyl-1,3-cyclopentanedione and 2-methyl-1,3-cyclohexanedione

  • G. V. Kondrat'eva
  • G. A. Kogan
  • T. M. Fadeeva
  • S. I. Zav'yalov
Organic and Biological Chemistry


As compared with 2-methyl-1,3-cyclohexanedione, 2-methyl-1,3-cyclopentanedione reacts with greater difficulty with nucleophilic reagents at the carbonyl groups and with electrophilic reagents at the methylidyne group.


Carbonyl Cyclohexanedione Carbonyl Group Great Difficulty Cyclopentanedione 
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Literature cited

  1. 1.
    S. I. Zav'yalov and L. P. Vinogradova, Izv. AN SSSR, Otd. Khim. N.,1961, 1640.Google Scholar
  2. 2.
    S. I. Zav'yalov and G V Kondrat'eva, Izv. AN SSSR, Otd. Khim. N.,1960, 1429.Google Scholar
  3. 3.
    H. C. Brown and K. Ichikawa, Tetrahedron, 1, 221 (1957).Google Scholar
  4. 4.
    I. N. Nazarov and S. I. Zav'yalov, Zh. obshch. khimii,23, 1703 (1953).Google Scholar
  5. 5.
    H. Smith, J. Chem. Soc.,1953, 803.Google Scholar
  6. 6.
    W. Klyne and P. B. D. de la Mare, Progress in Stereochemistry, London,1958, 2, p. 101.Google Scholar
  7. 7.
    I. N. Nazarov and S. I. Zav'yalov, Zh. obshch. khimii,24, 469 (1954).Google Scholar
  8. 8.
    S. I. Zav'yalov and V. M. Medvedeva, Izv. AN SSSR, Otd. Khim. N.,1959, 2165.Google Scholar
  9. 9.
    I. N. Nazarov and S. I. Zav'yalov, Izv. AN SSSR, Otd. Khim. N.,1952, 300.Google Scholar
  10. 10.
    C. B. C. Boyce and J. S. Whitehurst, J. chem. Soc.1959, 2022.Google Scholar
  11. 11.
    J. N. Nazarov, S. N. Ananchenko, and I. V. Torgov, Zh. obshch. khimii,26, 819 (1956).Google Scholar
  12. 12.
    E. C. Horning, M. G. Horning, and E. J. Platt, J. Amer. Chem. Soc.,71, 1771 (1949).Google Scholar
  13. 13.
    E. E. Blaise, Compt. rend.,173, 314 (1921).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • G. V. Kondrat'eva
    • 1
  • G. A. Kogan
    • 1
  • T. M. Fadeeva
    • 1
  • S. I. Zav'yalov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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