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Reaction of phenyl compounds of group III elements with benzene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The thermal decomposition of (C6H5 3Al, (C4H5Ga, (C6H5)3In, (C6H5)3 Tl in C14-labeled benzene solution is accompanied by the exchange of their phenyl radicals with the solvent. Triphenylaluminum shows the greatest ability to exchange. Triphenylgallium exchanges with benzene with much greater difficulty than does triphenylaluminum, and the ability to exchange increases in the order (C6H5Ga, (C6H5)3In, (C6H5)3Tl.

  2. 2.

    The exchange reaction is not observed in the photodecomposition of the organometallic compounds [(C6H5In].

  3. 3.

    The phenyl radicals of the organometallic compounds react with benzene to yield biphenyl.

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Literature cited

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Authors and Affiliations

  1. Scientific-Research Institute of Chemistry, N. I. Lobachevskii State University, Gorki

    G. A. Razuvaev, Yu. A. Kaplin & E. V. Mitrofanova

Authors
  1. G. A. Razuvaev
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  2. Yu. A. Kaplin
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  3. E. V. Mitrofanova
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Additional information

Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1489–1491, August, 1965 Original article submitted November 27, 1964

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Razuvaev, G.A., Kaplin, Y.A. & Mitrofanova, E.V. Reaction of phenyl compounds of group III elements with benzene. Russ Chem Bull 14, 1455–1457 (1965). https://doi.org/10.1007/BF00846215

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  • DOI: https://doi.org/10.1007/BF00846215

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