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The action of tetra-n-propyldiborane on n-butyl vinyl ether and esters of allyboric and allylthioboric acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When tetra-n-propyldiborane acts on n-butyl vinyl ether, di-n-propyl-(2-n-butoxyethyl)boron is formed, which is converted at room temperature with evolution of ethylene to the n-butyl ester of di-n-propylboric acid.

  2. 2.

    Tetra-n-propyldiborane adds to esters of allyl- and allylthioboric acid with the formation of unstable din-propyl-(2-methoxyborylpropyl) boron or di-n-propyl-(2-methylmercaptopropyl)boron, which decompose to esters of di-n-propylboric or di-n-propylthioboric acids and polymers (-CH2- CH2-CH2B-X)n.

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Literature cited

  1. B. M. Mikhailov and A. N. Blokhina, Izv. AN SSSR Otd. khim. n. 1373 (1962).

  2. B. M. Mikhailov and L. S. Vasil'ev, Izv. AN SSSR Otd. khim. n. 531 (1961).

  3. B. M. Mikhailov and V. F. Pozdnev, Izv. AN SSSR Otd. khim. n. 1861 (1962).

  4. B. M. Mikhailov, A. A. Akhnazaryan, and L. S. Vasil'ev, Dokl. AN SSSR136, 828 (1961).

    Google Scholar 

  5. B. M. Mikhailov and T. A. Shchegoleva, Zh. Obshch. khimii29, 3130 (1959).

    Google Scholar 

  6. B. M. Mikhailov and V. F. Pozdnev, Dokl. AN SSSR157, 577 (1963).

    Google Scholar 

  7. B. M. Mikhailov and Yu. N. Bubnov, Izv. AN SSSR Otd khim. n. 1649 (1959).

  8. B. M. Mikhailov and V. F. Pozdnev, Izv. AN SSSR Otd. khim. n. 861 (1962).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences, USSR

    B. M. Mikhailov & E. N. Safonova

Authors
  1. B. M. Mikhailov
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  2. E. N. Safonova
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Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1487–1489, August, 1965 Original article submitted November 25, 1964

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Mikhailov, B.M., Safonova, E.N. The action of tetra-n-propyldiborane on n-butyl vinyl ether and esters of allyboric and allylthioboric acids. Russ Chem Bull 14, 1452–1454 (1965). https://doi.org/10.1007/BF00846214

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  • DOI: https://doi.org/10.1007/BF00846214

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