Conclusions
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1.
The halogen atom in C-halobarenes possesses a positive character.
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2.
The corresponding halo-2-phenylbarenes were produced under the action of chlorine, bromine, and iodine on phenylbarenyllithium.
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Literature cited
L. I. Zakharkin, V. I. Stanko, A. I. Klimova, and Yu. A. Chapovskii, Izv. AN SSSR, Ser. Khim., 2236 (1963).
L. I. Zakharkin and Yu. A. Chapovskii, Tetrahedron Letters 1147 (1964).
D. Grafstein, J. Bobinski, J. Dvorak, H. Smith, N. Schwarz, M. Cohen, and M. Fein, Inorgan. Chem.2, 1120 (1963).
T. Heying, J. Ager, L. Clark, R. Alexander, S. Papetti, A. Reid, and S. Trotz, Inorgan. Chem.2 1097 (1963).
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Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1464–1466, August, 1965 Original article submitted November 19, 1964
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Zakharkin, L.I., Podvisotskaya, L.S. The “positive” nature of the halogen atom in C-halobarenes. Russ Chem Bull 14, 1422–1424 (1965). https://doi.org/10.1007/BF00846204
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DOI: https://doi.org/10.1007/BF00846204