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Interaction of B-methyl-N- triphenylborazole with diisocyanates and diamines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Copolymerization of B-methyl-N-triphenylborazole with hexamethylenediisocyanate, p-toluylenediisocyanate, and 4,4′-diphenylenediisocyanate yielded low-molecular polyalkylenedicarbaminoyl- and polyarylenedicarbaminoyl-B, B′-boroazolylenes, stable to the action of atmospheric moisture.

  2. 2.

    Polyalkylenediimino- and polyarylenediimino-B,B′-boroazolylenes, which hydrolyze in air, were characterized after synthesis by polycondensation of B-methyl-N-triphenylborazole with hexamethylenediamine and p-phenylenediamines.

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Literature cited

  1. V. V. Korshak, V. A. Zamyatina, and R. M. Oganesyan, Izv. AN SSSR, Otd. Khim. N. 1669 (1962).

  2. B. M. Mikhailov and A. F. Galkin, Izv. AN SSSR, Otd. Khim. N. 641 (1963).

  3. U. S. Patent 2998449, 29. VIII (1961); RZhKhim, 17 L 17 (1962).

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Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1462–1464, August, 1965 Original article submitted November 3, 1964

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Korshak, V.V., Bekasova, N.I. & Komarova, L.G. Interaction of B-methyl-N- triphenylborazole with diisocyanates and diamines. Russ Chem Bull 14, 1419–1421 (1965). https://doi.org/10.1007/BF00846203

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  • DOI: https://doi.org/10.1007/BF00846203

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