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Polymerization of 1,1 -disubstituted silacyclopentanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the transformations of 1-substituted and 1, 1-disubstituted silacyclopentanes (substituents: alkyls, aryls, chlorine, and alkyls with functional groups) at 20–120° in presence of metal halides.

  2. 2.

    At 20° or higher in presence of catalytic amounts of aluminum chloride silacyclopentanes with one or two alkyl substituents on silicon polymerize. Hetero-chain sila-hydrocarbon polymers are formed with silicon in the main chain and a molecular weight of 1 · 103-2.5 · 103.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences, USSR

    N. S. Nametkin, V. M. Vdovin, K. S. Pushchevaya & V. I. Zav'yalov

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  1. N. S. Nametkin
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  2. V. M. Vdovin
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  3. K. S. Pushchevaya
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  4. V. I. Zav'yalov
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Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1453–1459, August, 1965 Original article submitted June 28, 1963

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Nametkin, N.S., Vdovin, V.M., Pushchevaya, K.S. et al. Polymerization of 1,1 -disubstituted silacyclopentanes. Russ Chem Bull 14, 1411–1415 (1965). https://doi.org/10.1007/BF00846201

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  • DOI: https://doi.org/10.1007/BF00846201

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