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Use of dilithium compounds for the synthesis of fluorinated unsaturated compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The application of aliphatic dilithium compounds in the synthesis of the fluorinated dienes CF2=CF(CH2)-nCF=CF2.

  2. 2.

    1,1,8,8,8-Hexafluoro-2,7-dimethyl-2,7-octanediol and 1,1,8,8-tetrafluoro-2,7-octanedione was prepared for the first time.

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Literature cited

  1. R. West and E. Rochow, J. Organ. Chem.18, 1739 (1953); R. West, J. Amer. Chem. Soc.76, 6012 (1954); D. Wittenberg and H. Oilman, J. Amer. Chem. Soc.80, 2678 (1958).

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  2. E. Kenneth, U.S. Pat. 2947793 (Aug. 2, '60); RZhKhim. 22L68 (1961).

  3. S. Dixon, U.S.Pat. 2848504 (Aug. 19, '58); RZhKhim, 48848 (1960).

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Authors and Affiliations

  1. A. Ya. Karpov Physicochemical Institute, USSR

    T. V. Talalaeva, O. P. Petrii, A. V. Zimin & K. A. Kochetkov

Authors
  1. T. V. Talalaeva
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  2. O. P. Petrii
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  3. A. V. Zimin
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  4. K. A. Kochetkov
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Additional information

Translated from Izvestiya Akadeemii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1402–1405, August, 1965 Original article submitted June 25, 1963

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Talalaeva, T.V., Petrii, O.P., Zimin, A.V. et al. Use of dilithium compounds for the synthesis of fluorinated unsaturated compounds. Russ Chem Bull 14, 1364–1366 (1965). https://doi.org/10.1007/BF00846193

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  • DOI: https://doi.org/10.1007/BF00846193

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