Conclusions
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1.
The mechanism of the reaction of the HO2 radical with molecules of saturated and unsatured hydrocarbons and methanol was studied.
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2.
The HO2 radical reacts with molecules of saturated hydrocarbons with cleavage of the C-C bond and the formation of a carbonyl compound and hydroxyl. All the way up to a temperature of 200°, the reaction of stripping of a H atom is negligible.
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3.
With molecules of unsaturated hydrocarbons at temperatures up to 200°, the characteristic reaction is addition to the double bond, followed by the formation of a carbonyl compound and an alcohol radical.
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4.
The main reaction of HO2 with methanol is the formation of H2O2 and a CH2OH radical.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1336–1345, August, 1965 Original article submitted June 28, 1963
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Avramenko, L.I., Evlashkina, L.M. & Kolesnikova, R.V. Reactions of the HO2 radical Communication 1. Mechanism of interaction of HO2 radicals with saturated and unsaturated hydrocarbons and methanol. Russ Chem Bull 14, 1306–1313 (1965). https://doi.org/10.1007/BF00846183
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DOI: https://doi.org/10.1007/BF00846183