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Formation of radicals in the reaction of oxygen with styrene and cobalt

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A radical-forming reaction in hydrocarbon solution between styrene, oxygen, and CoII in the form of its stearate and acetylacetonate has been established. The kinetic laws of this reaction have been studied. A mechanism has been proposed which consists in the formation of a complex between the oxygen and the CoII by a reversible reaction, with the subsequent reaction of this complex with styrene to form free radicals.

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Literature cited

  1. E. T. Denisov and N. M. Émanuél, Zh. fiz. khimii,30, 2499 (1956).

    Google Scholar 

  2. N. Uri, Nature177, 1177 (1954).

    Google Scholar 

  3. L. N. Denisova and E. T. Denisov, Izv. AN SSSR, Ser. khim.,1965, 1702.

  4. F. Gach. Monatsh.21, 105 (1900).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    L. N. Denisova, E. T. Denisov & T. G. Degtyareva

Authors
  1. L. N. Denisova
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  2. E. T. Denisov
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  3. T. G. Degtyareva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1095–1097, June, 1966.

The authors express their thanks to I. I. Uskov and A. L. Aleksandrov for help in performing some of the experiments.

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Denisova, L.N., Denisov, E.T. & Degtyareva, T.G. Formation of radicals in the reaction of oxygen with styrene and cobalt. Russ Chem Bull 15, 1048–1050 (1966). https://doi.org/10.1007/BF00846070

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  • DOI: https://doi.org/10.1007/BF00846070

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