Conclusions
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1.
The oxidation of hexenes and decenes with various positions of the double bond in the molecular chain by monoperphthalic acid was conducted for the first time. The epoxy compounds thus obtained were isolated and characterized.
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2.
The theoretical possibility of the isolation of alkanes from the catalyzates of selective hydrogenation of n-hexane and n-decane in the form of the corresponding epoxy compounds was demonstrated.
Literature cited
D. Svern, Collection; Organic Reaction [Russian translation], No. 7, IL, Moscow, 1956, p. 477.
A. Cross, Introduction to Practical Infrared Spectroscopy [Russian translation], IL, Moscow, 1961, p. 86.
L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL, Moscow, 1963.
E. A. Timofeeva, N. I. Shuikin, Yu. N. Plotnikov, and V. M. Kleimenova, Dokl. AN SSSR,125, 1272 (1959);129, 128 (1959).
Modern Methods of Experimentation in Organic Chemistry [in Russian], Goskhimizdat, Moscow, 1960, p. 384.
B. Rotstein, Bull. Soc. chim. France (5),2, 1936 (1935).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1088–1089, June, 1966.
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Polyakova, A.M., Vinogradova, O.V., Korshak, V.V. et al. Production of epoxy compounds by the oxidation of decenes and hexenes by monoperphthalic acid. Russ Chem Bull 15, 1039–1040 (1966). https://doi.org/10.1007/BF00846065
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DOI: https://doi.org/10.1007/BF00846065