Reaction ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides with certain nucleophilic agents

  • A. A. Volod'kin
  • V. V. Ershov
  • G. D. Ostapets-Sveshnikova
  • I. S. Belostoskaya
Brief Communications
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Conclusions

  1. 1.

    Eightα-alkyl-4-hydroxy-3,5-ditert-butylbenzyl halides were produced by addition of the hydrogen halides toα-alkyl-2,6-ditert-butylmethylenequinones.

     
  2. 2.

    α-Alkyl-4-hydroxy-3,5-ditert-butylbenzonitriles and 4-(α-N,N-dialkylamino)alkyl-2,6-ditert-butylphenols were produced by the reactions ofα-alkyl-4-hydroxy-3,5-ditert-butylbenzylbromides (chlorides) with sodium cyanide and secondary amines.

     
  3. 3.

    A new method of synthesizing 4-sec-alkyl-2, 6-ditert-butylphenols was proposed.

     

Keywords

Hydrogen Sodium Chloride Cyanide Halide 

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • A. A. Volod'kin
    • 1
  • V. V. Ershov
    • 1
  • G. D. Ostapets-Sveshnikova
    • 1
  • I. S. Belostoskaya
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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