Conclusions
The addition of benzenesulfenyl chloride to acrylonitrile gives a mixture of the isomeric 2-chloro-3-(phenylthio)- and 3-chloro -2-(phenylthio)-propionitriles with a predominance of the latter.
Similar content being viewed by others
Literature cited
M. G. Lin'kova, N. D. Patrina, and I. L. Knunyants, Dokl. AN SSSR127, 799 (1959); I. L. Knunyants, N. D. Kuleshova, and M. G. Lin'kova, Dokl. AN SSSR135, (1960).
S. A. Helninger and G. H. Birum, U. S. Patent 3018304, 1957; Chem. Abstrs.56, 15429 (1962); U. S. Patent 3044927, 1957; Chem. Abstrt.57, 15013 (1962); U. S. Patent 3050545, 3063894, 3064036, 1962; Chem. Abstrs.58, 1405, 8977, 6754 (1963); L. A. Miller, U. S. Patent 3040086, 1959; Chem. Abstrs. 15013, 1962.
K.-D. Gundermann, Chem. Ber.89, 1963 (1956).
O. Achmatowicz and J. Michalski, Roczniki chem.30, 243 (1956); Chem. Abstrs,51, 1064 (1957); E. I. Grinblat and I. Ya. Postovskii, Zh. obshch. khimii31, 389 (1961); G. Kresze, W. Schramm, and G. Cleve, Chem. Ber.94, 2060 (1961); Chem. Abstrs.55, 25829 (1961).
H. J. Backer, Bull. Soc. chim. France1950, 724.
F. Montanari and A. Nigrini, Gazz. chim. ital.87, 1073 (1957); Chem. Abstrs.52, 9988 (1958).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1075–1080, June, 1966.
Rights and permissions
About this article
Cite this article
Knunyants, I.L., Lin'kova, M.G. & Veller, N.L. Structure of products of the addition of benzenesulfenyl chloride to acrylic acid derivatives. Russ Chem Bull 15, 1025–1029 (1966). https://doi.org/10.1007/BF00846060
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00846060