Conclusions
When alkanesulfenyl chlorides are added to acrylic derivatives CH2=CHR (R=COOH, COOCH3, COOCH3 CN, CONH2 a mixture of the isomers\(\begin{gathered} CH_2 - CH - R \hfill \\ | | \hfill \\ Cl SR' \hfill \\ \end{gathered} \) and\(\begin{gathered} CH_2 - CH - R \hfill \\ | | \hfill \\ SR' Cl \hfill \\ \end{gathered} \) is formed and the proportions of these depend on the nature of the substituent R.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1069–1075, June, 1966.
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Knunyants, I.L., Lin'kova, M.G. & Kuleshova, N.D. Structure of products of the addition of methane- and ethane-sulfenyl chlorides to acrylic acid derivatives. Russ Chem Bull 15, 1020–1024 (1966). https://doi.org/10.1007/BF00846059
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DOI: https://doi.org/10.1007/BF00846059