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Mobility of hydrogen atoms in mono-H-polyfluoroalkanes and related compounds Communication 2. 2H-hexafluoro-2-(trifluoromethyl)propane in the Michael reaction

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

For the first time the proton mobility of hydrogen atoms in mono-H-polyfluoroalkanes due to the electron-attracting action of perfluoroalkyl groups was applied in synthesis. By Michael reactions with 2H-hexafluoro-2-(trifluoromethyl)propane various derivatives of 5, 5, 5-trifluoro-4,4-bistrifluoromethyl-valeric acid were prepared, and from these a number of compounds containing the perfluoro-t-butyl group were synthesized.

Michael reactions were also conducted with 3,3,3-trifluoro-2-(trifluoromethyl)propionic and (trifluoromethyl)malonic esters.

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Literature cited

  1. I. L. Knunyants, S. T. Kocharyan, Yu. A. Cheburkov, M. D. Bargamova, and E. M. Rokhlin, Dokl. ANSSSR165, 827 (1965).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    I. L. Knunyants, S. T. Kocharyan & E. M. Rokhlin

Authors
  1. I. L. Knunyants
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  2. S. T. Kocharyan
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  3. E. M. Rokhlin
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Additional information

For communication 1 see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1057–1062, June, 1966.

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Knunyants, I.L., Kocharyan, S.T. & Rokhlin, E.M. Mobility of hydrogen atoms in mono-H-polyfluoroalkanes and related compounds Communication 2. 2H-hexafluoro-2-(trifluoromethyl)propane in the Michael reaction. Russ Chem Bull 15, 1008–1012 (1966). https://doi.org/10.1007/BF00846056

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  • DOI: https://doi.org/10.1007/BF00846056

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