Conclusions
-
1.
Unlike other known ketenes, bistrifluoromethylketene forms a linear dimer under the action of triethylamine.
-
2.
A new reaction was discovered: the linear dimerization of functional derivatives of perfluoromethacrylic and (difluoromethylene)malonic acids.
Similar content being viewed by others
Literature cited
W. Henford and D. Sauer, Organic Reactions, Collection 3 [Russian translation], IL, Moscow, 1951, p. 110.
R. Hasek, R. Clark, E. Elam, and J. Martin, J. Organ. Chem.27, 60 (1962).
Yu. A. Cheburkov, M. D. Bargamova, and I. L. Knunyants, Izv. AN SSSR. Ser. khim. Izv.1963, 1393.
Yu. A. Cheburkov, N. Mukhamadaliev, and I. L. Knunyants, Izv.1965, 1476.
Yu. A. Cheburkov and I. L. Knunyants, Izv.1963, 1573.
J. Pople, W. Schneider, and H. Bernstein, High-Resolution Nuclear Magnetic Resonance [Russian translation], IL, Moscow, 1962, p. 405.
N. Bhacca, L. Johnson, and J. Shoolery. “NMR Spectra Catalog.” Varian Associates, Palo Alto, Calif., 1962.
Yu. A. Cheburkov and I. L. Knunyants, Authors' Certificate USSR No. 148,042 and 144,480.
B. L. Dyatkin, E. P. Mochalina, L. T. Lantseva, and I. L. Knunyants, Zh. Vses. khim. obshch. im D. I. Mendeleeva10, 469 (1965).
Yu. A. Cheburkov, N. Mukhamadaliev, Yu. E. Aronov, and I. L. Knunyants, Izv.1965, 1478.
Yu. A. Cheburkov and I. L. Knunyants, Izv. (in the press).
M. D. Bargamova, Yu. A. Cheburkov, P. V. Petrovskii, B. L. Dyatkin, and I. L. Knunyants, Izv. (in the press).
I. L. Knunyants, V. V. Tyuleneva, and V. V. Shokina, Dokl. AN SSSR (in the press).
S. T. Kocharyan, Yu, A. Cheburkov, M. D. Bargamova, E. M. Rokhlin, and I. L. Knunyants, Dokl. AN SSSR165, 827 (1965).
Yu. A. Cheburkov, M. D. Bargamova, and I. L. Knunyants, Izv.1964, 367.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimiceskaya, No. 6, pp. 1031–1038, June, 1966.
Rights and permissions
About this article
Cite this article
Knunyants, I.L., Cheburkov, Y.A., Bargamova, M.D. et al. Bistrifluoromethylketene Communication 7. Structure of the dimer. Russ Chem Bull 15, 985–991 (1966). https://doi.org/10.1007/BF00846053
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00846053