Conclusions
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1.
Previously unknown alkyl trifluorovinyl sulfates were obtained by the reactions of tetrafluoro-2-hydroxyethanesulfonicβ-sultone with dialkyl sulfates and dialkyl sulfites.
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2.
The reactions of tetrafluoro-2-hydroxyethanesulfonicβ-sultone with alkyl sulfites provide a general method for the preparation of alkyl trifluorovinyl sulfates.
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3.
A value of 9.82 was deduced for the refraction of the trifluorovinyl gro ip.
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Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 6, pp. 1022–1027, June, 1966.
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Knunyants, I.L., Sokol'skii, G.A. & Belaventsev, M.A. Fluorine-containingβ-sultones Communication 16. Alkyl trifluorovinyl sulfates. Russ Chem Bull 15, 977–980 (1966). https://doi.org/10.1007/BF00846051
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DOI: https://doi.org/10.1007/BF00846051