Fluorine-containingβ-sultones Communication 15. Alkyl fluorosulfates

  • U. L. Knunyants
  • G. A. Sokol'skii
  • M. A. Belaventsev
Organic and Biological Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    In the reactions of tetrafluoro-2-hydroxyethanesulfonicβ-sultone with methane sulfonyl chloride, with alkyl chlorosulfates, and with sulfuryl chloride trifluorovinyl chlorosulfate is formed together with the corresponding fluorosulfonyl compounds.

     
  2. 2.

    The reactions of fluorine-containingβ-sultones with alkyl chlorosulfates provide a general method for the preparation of previously inaccessible alkyl fluorosulfates.

     
  3. 3.

    The main functional peculiarity of alkyl fluorosulfates is their great alkylating power.

     
  4. 4.

    It was deduced that the fluorosulfonyloxy group has a refraction\(ROSO_2 F\) of 11.50.

     

Keywords

Chloride Methane Refraction Sulfonyl Sulfonyl Chloride 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Dokl. AN SSSR159, 135 (1964); G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. AN SSSR. Ser. khim.1965, 1804.Google Scholar
  2. 2.
    M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. AN SSSR. Ser. khim.1965, 1613.Google Scholar
  3. 3.
    W. Traube, German Patent 346, 245, December 27, 1921; Chem. Zbl.1922, 2, 572; J. Meyer and G. Schramm, Z. anorgan. and allgem. Chem.206, 24 (1932); S. B. Linn, U. S. Patent 2,428,755 October 7, 1947; Chem. Abstrs42, 921 (1948).Google Scholar
  4. 4.
    B. W. Joffe, Chemist's Guide to Refractometry [Russian translation], IL, Moscow, 1956, p. 176.Google Scholar
  5. 5.
    G. A. Sokol'skii and I. L. Knunyants, Izv. AN SSSR. Otd. khim. n.1961, 1606.Google Scholar

Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • U. L. Knunyants
  • G. A. Sokol'skii
  • M. A. Belaventsev

There are no affiliations available

Personalised recommendations