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Hydrogen exchange of saturated hydrocarbons in homogeneous media Communication 3. Ionic-chain mechanism of the reaction of isotopic exchange of the hydrogen of methylcyclohexane in solutions of trifluoroacetic and sulfuric acids

  • D. N. Kursanov
  • V. N. Setkina
  • N. V. Fok
Physical Chemistry
  • 32 Downloads

Conclusions

  1. 1.

    An ionic-chain mechanism of the isotopic exchange of the hydrogen of methylcyclohexane in acid media was demonstrated by comparing the rate of isotopic exchange of hydrogen and the rate of absorption of bromine by methylcyclohexane in a solution of trifluoroacetic and sulfuric acids.

     
  2. 2.

    Participation of the olefin in the reaction of isotopic exchange of the hydrogen of methylcyclohexane in acid media was demonstrated.

     

Keywords

Hydrogen Hydrocarbon Sulfuric Acid Bromine Acid Medium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • D. N. Kursanov
    • 1
  • V. N. Setkina
    • 1
  • N. V. Fok
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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