Conclusions
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1.
The influence of substituents in the aryldiazonium cation on the yields of products of radical reactions and reactions proceeding according to a heterolytic mechanism was considered.
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2.
It was hypothesized that the Sandmeyer reaction proceeds according to a radical mechanism.
-
3.
The heterolytic mechanism of the Nesmeyanov reaction was confirmed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 966–973, June, 1966.
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Kikot', V.S., Kazitsyna, L.A. & Reutov, O.A. On the mechanism of certain reactions proceeding with the participation of diazonium salts. Russ Chem Bull 15, 924–930 (1966). https://doi.org/10.1007/BF00846041
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DOI: https://doi.org/10.1007/BF00846041