Conclusions
-
1.
Triethylaluminum does not react with vinyl chloride at temperatures up to 60°. The presence of traces of titanium trichloride catalyzes the reaction of dehydrochlorination of vinyl chloride.
-
2.
The ability of vinyl chloride for the dehydrochlorination reaction increases in the direction from triethylaluminum to aluminum chloride.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
V. S. Étlis, K. S. Minsker, E. E. Rylov, and D. N. Bort, Vysokomolekul. Soed.,1, 1403 (1959).
G. A. Razuvaev, A. I. Graevskii, K. S. Minsker, Z. S. Smolyan, G. T. Fedoseeva, and D. N. Bort, Ibid.,5, 1030 (1963).
Belgian patent 646600, 30/III (1956); N. Gaylord and G. Mark, “Linear and Stereoregular Polymers” [Russian translation], Moscow (1962), p. 237.
R. Köster and W. R. Kroll, Liebigs. Ann. Chem.,629, 50 (1960); Collection: Organoaluminum Compounds [Russian translation], IL., Moscow (1962), pp. 67–68.
G. A. Razuvaev and A. I. Graevskii, Transactions on Chemistry and Chemical Technology [in Russian], Gor'kii,3, 611 (1959).
G. Wilke and H. Müller, Liebigs. Ann. Chem.,629, 222 (1960); Collection: Organoaluminum Compounds [Russian translation], IL., Moscow (1962), p. 275.
G. A. Razuvaev and A. I. Graevskii, Dokl. AN SSSR,128, 399 (1959).
Yu. Newland and R. Vogt, Acetylene Chemistry [Russian translation], IL., Moscow (1947), p. 64.
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 658–661, April, 1966
Rights and permissions
About this article
Cite this article
Razuvaev, G.A., Minsker, K.S., Sangalov, Y.A. et al. Interaction of vinyl chloride with certain organoaluminum compounds. Russ Chem Bull 15, 624–626 (1966). https://doi.org/10.1007/BF00845939
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00845939