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Kinetics of the reaction of tetranitromethane with certain reducing agents

  • M. Sh. L'vova
  • V. I. Slovetskii
  • A. A. Fainzil'berg
Physical Chemistry

Conclusions

  1. 1.

    The kinetics of the reactions of tetranitromethane with reducing agents, which act as denitrating agents — potassium nitrite and potassium iodide in 70% ethanol — were studied.

     
  2. 2.

    The reactions studied proceed according to a total second order and are first order with respect to each of the components: with respect to tetranitromethane and with respect to the denitrating agent.

     
  3. 3.

    The instability constant of the complex I3 in 70% ethanol was found.

     
  4. 4.

    A method was proposed for quantitative determination of tetranitromethane.

     

Keywords

Potassium Nitrite Iodide Quantitative Determination Potassium Iodide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • M. Sh. L'vova
    • 1
  • V. I. Slovetskii
    • 1
  • A. A. Fainzil'berg
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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