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Synthesis and certain transformations of vinylsilyl esters of glycols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Vinyl esters containing the trimethylsiloxy group were produced by the reaction of trimethylchlorosilane with monovinyl ethers of glycols in the presence of pyridine.

  2. 2.

    The addition of ethyl mercaptan to vinyl trimethylsilyl esters of glycols according to a radical mechanism was used to synthesize the corresponding organosilicon sulfides.

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Literature cited

  1. M. I. Hurwitz and P. L. DeBenneville, U. S. Patent, 2865899 (1958); Chem. Abstrs,53, 5735 (1959).

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  2. M. F. Shostakovskii, E. N. Prilezhaeva, and S. Shapiro, Izv. AN SSSR. Otd. Khim. N., 357 (1953).

  3. M. F. Shostakovskii, Simple Vinyl Esters [in Russian], Izd. AN SSSR, Moscow (1962), p. 261.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Department, Academy of Sciences USSR, USSR

    M. F. Shostakovskii, A. S. Atavin, V. M. Nikitin, B. A. Trofimov, V. V. Keiko & V. I. Lavrov

Authors
  1. M. F. Shostakovskii
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  2. A. S. Atavin
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  3. V. M. Nikitin
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  4. B. A. Trofimov
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  5. V. V. Keiko
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  6. V. I. Lavrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2049–2051, November 1965

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Shostakovskii, M.F., Atavin, A.S., Nikitin, V.M. et al. Synthesis and certain transformations of vinylsilyl esters of glycols. Russ Chem Bull 14, 2014–2016 (1965). https://doi.org/10.1007/BF00845904

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  • DOI: https://doi.org/10.1007/BF00845904

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