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Reactions of bis-2-chloroethyl and bis[2-(2-chloroethoxy)ethyl] cis-4-cyclohexene-1,2-dicarboxylates with sodium alkoxides

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reactions of bis-2-chloroethyl and bis[2-(2-chloroethoxy)ethyl] cis-4-cyclohexene-1,2-dicarboxylates with sodium alkoxides were investigated.

  2. 2.

    Reaction occurs with the transesterification of the chloroethoxy (or chloroethoxyethoxy) group in the bis-2-chloroethyl or bis[2-(2-chloroethoxy)ethyl] cis-4-cyclohexene-1,2-dicarboxylate for the alkoxy of the alkoxide.

  3. 3.

    Under the conditions of the reaction, simultaneously with transesterification the isomerization of cis-4-cyclohexene-1,2-dicarboxylic esters into their trans isomers occurs.

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Literature cited

  1. L. A. Mukhamedova and M. Kh. Baiburova, Neftekhimiya3, 900 (1963).

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  2. Dictionary of Organic Compounds [Russian translation],2, IL (1949), p. 248.

  3. A. A. Petrov and N. P. Sopov, Collection of Articles on General Chemistry [in Russian],2, (1953), p. 853.

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  4. L. A. Mukhamedova, M. Kh. Baiburova, T. M. Malyshko, and M. I. Kudryavtseva, Neftekhimiya1, 88 (1961).

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the USSR, Kazan'

    L. A. Mukhamedova, M. Kh. Baiburova & R. R. Shagidullin

Authors
  1. L. A. Mukhamedova
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  2. M. Kh. Baiburova
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  3. R. R. Shagidullin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2019–2024, November 1965

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Mukhamedova, L.A., Baiburova, M.K. & Shagidullin, R.R. Reactions of bis-2-chloroethyl and bis[2-(2-chloroethoxy)ethyl] cis-4-cyclohexene-1,2-dicarboxylates with sodium alkoxides. Russ Chem Bull 14, 1983–1987 (1965). https://doi.org/10.1007/BF00845895

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  • DOI: https://doi.org/10.1007/BF00845895

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