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Syntheses from 4,5-dibromo-2-furaldehyde

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The nitration of 4,5-dibromo-2-furaldehyde with nitric acid in acetic anhydride goes with the replacement of the bromine atom in the α-position of the furan nucleus by a nitro group, and 4-bromo-5-nitro-2-furanmethanediol diacetate is formed.

  2. 2.

    In the reaction of butyllithium with 4,5-dibromo-2-furaldehyde acetal the bromide in the α-position of the furan nucleus is replaced by lithium.

  3. 3.

    It was shown that from 4,5-dibromo-2-furaldehyde it is possible to prepare some new difficultly accessible furan compounds with three substituants in the nucleus.

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Literature cited

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    L. D. Tarasova & Ya. L. Gol'dfarb

Authors
  1. L. D. Tarasova
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  2. Ya. L. Gol'dfarb
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Additional information

This article is published in accordance with a resolution of the Conference of Editors-in-Chief of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by L. D. Tarasova.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2013–2019, November 1965

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Tarasova, L.D., Gol'dfarb, Y.L. Syntheses from 4,5-dibromo-2-furaldehyde. Russ Chem Bull 14, 1978–1982 (1965). https://doi.org/10.1007/BF00845894

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  • DOI: https://doi.org/10.1007/BF00845894

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