Preparation and rearrangement of alkyl phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphites

  • V. K. Khairullin
  • T. I. Sobchuk
Organic and Biological Chemistry

Summary

  1. 1.

    A study was made of the reactions of phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphorochloridite with alcohols with formation of phosphorous esters containing three different alkoxyls. The acid chloride does not react with 2,6-xylenol, probably because of the presence of steric hindrance.

     
  2. 2.

    The rearrangement of the alkyl phenyl 2,2,2-trichloro-1,1-dimethylethyl phosphities with methyl iodide goes with elimination of the unsubstituted aliphatic group.

     

Keywords

Alcohol Methyl Chloride Ester Phenyl 

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Literature cited

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Copyright information

© Consultants Bureau 1966

Authors and Affiliations

  • V. K. Khairullin
    • 1
  • T. I. Sobchuk
    • 1
  1. 1.Institute of Organic ChemistryAcademy of Sciences of the USSRKazan'

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