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Synthesis of the cis- and trans-isomers of decahydroquinoline and octahydro-1-pyrindine

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    In the verification of methods described in the literature for the stereospecific synthesis of cis- and trans-decahydroquinolines and cis- and trans-octahydro-1-pyrindines it was shown that in many cases mixtures of isomers are actually formed.

  2. 2.

    A convenient method is proposed for the synthesis of the cis isomers of decahydroquinoline and octahydro-1-pyrindine, and the probable mechanism of the reductive cyclization of 2-oxocyclohexane- and 2-oxocyclopentane-propionitrues is discussed.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    É. A. Mistryukov

Authors
  1. É. A. Mistryukov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2001–2005, November 1965

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Mistryukov, É.A. Synthesis of the cis- and trans-isomers of decahydroquinoline and octahydro-1-pyrindine. Russ Chem Bull 14, 1966–1969 (1965). https://doi.org/10.1007/BF00845891

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  • DOI: https://doi.org/10.1007/BF00845891

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