Summary
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1.
By the reaction of bistrifluoromethylketene with nitrosyl fluoride and with ethyl nitrite the acid fluoride and ethyl ester of 3,3,3-trifluoro-2-nitroso-2-(trifluoromethyl)propionic acid were obtained, and their properties were studied.
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2.
The reactions of bistrifluoromethylketene with sodium nitrite and with nitrous anhydride, leading to hexafluoroacetone oxime, were investigated.
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This article is published in accordance with a resolution of the Conference of Editors-in-Chief of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by N. Mukhamadaliev.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1982–1987, November 1965
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Mukhamadaliev, N., Cheburkov, Y.A. & Knunyants, I.L. Bistrifluoromethylketene Communication 6. Reactions with nitrous acid derivatives. Russ Chem Bull 14, 1949–1953 (1965). https://doi.org/10.1007/BF00845887
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DOI: https://doi.org/10.1007/BF00845887