Conclusions
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1.
The activation energies of the dehydrogenation and dehydration of ethanol, n-propanol, isopropanol, n-butanol, and isobutanol, the dehydrogenation of tetralin, and the dehydration of tert-butanol on Tm2O3 were determined.
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2.
Alkyl substituents on the α-carbon atom influence the bond energies of C, H, and O with Tm2O3.
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A. A. Tolstopyatova, A. A. Balandin and PengP'i-hsiang, Izv. AN SSSR, Otd. Khim. N., 1524 (1962),
A. A. Balandin, A. A. Tolstopyatova and Peng P'i-hsiang, Izv. AN SSSR, Otd. Khim, N., 974 (1962).
A. A. Tolstopyatova, K. D. Tarlykova and Peng P'i-hsiang, Izv. AN SSSR, Ser. Khim., 1751 (1965).
V. V. Serebrennikov, Chemistry of the Rare Earth Elements [in Russian],1, Tomsk (1959).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1953–1960, November 1965
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Tolstopyatova, A.A., Balandin, A.A. & P'i-hsiang, P. Catalytic properties of thulium oxide in reactions of dehydrogenation and dehydration of alcohols and dehydrogenation of tetralin. Russ Chem Bull 14, 1923–1928 (1965). https://doi.org/10.1007/BF00845883
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DOI: https://doi.org/10.1007/BF00845883