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Investigation of the kinetics of the interaction of chlorosilanes with chlorobenzene in the gas phase

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of high-temperature interaction of chlorosilanes with chlorobenzene is well described by the equation of a second-order reaction.

  2. 2.

    The effective rate constants and activation energies of the reactions of trichlorosilane and methyldichlorosilane with chlorobenzene were determined within the temperature interval 580–680°.

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Literature cited

  1. E. A. Chernyshev, Li Kuang-liang, and A. D. Petrov, Dokl. AN SSSR,127, 808 (1959).

    Google Scholar 

  2. E. A. Chernyshev, V. F Mironov, and A. D. Petrov, Izv. AN SSSR, Otd. Khim. N., 2147 (1960).

  3. A. D. Petrov, E. A. Chernyshev, and Li Kuang-liang, Dokl. AN SSSR,137, 876 (1961).

    Google Scholar 

  4. G. M. Panchenkov and V. P. Lebedev, Chemical Kinetics and Catalysis [in Russian], Izd. MGU, Moscow (1961), p. 54.

    Google Scholar 

  5. V. N. Kondrat'ev, Kinetics of Chemical Gas Reactions [in Russian], Izd. AN SSSR, Moscow (1958), p. 227.

    Google Scholar 

  6. J. Hirschfelder, J. Chem. Phys.9, 645 (1941).

    Google Scholar 

  7. M. Szwarc, Chem. Rev.47, 75 (1950).

    Google Scholar 

  8. W. C. Steel, L. D. Nichols, and F. G. A. Stone, J. Amer. Chem. Soc.84, 4441 (1962).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. G. Bykovchenko, L. V. Érmanson & E. A. Chernyshev

Authors
  1. V. G. Bykovchenko
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  2. L. V. Érmanson
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  3. E. A. Chernyshev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1949–1953, November 1965

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Bykovchenko, V.G., Érmanson, L.V. & Chernyshev, E.A. Investigation of the kinetics of the interaction of chlorosilanes with chlorobenzene in the gas phase. Russ Chem Bull 14, 1919–1922 (1965). https://doi.org/10.1007/BF00845882

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  • DOI: https://doi.org/10.1007/BF00845882

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