Phenylgermanium derivatives of manganese carbonyl
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As a result of the reactions of the sodium salt of manganese carbonyl with phenylgermanium halide derivatives, we produced bimetallic compounds: (C6H5)3GeMn(CO)5, (C6H5)2Ge[Mn(CO)5]2 and [(C6H5)2GeMn(CO5]2.
(C6H5)3GeMn(CO)4P(C6H5)3, (C6H5)3GeMn(CO)4As(C6H5)3 and (C6H5)3GeMn(CO)4Sb(C6H5)3 were produced by replacement of the CO groups in the bimetallic compounds by phosphines, arsines, and stibines.
Under the action of halogens on phenylgermanium derivatives of manganese carbonyl, we produced (C6H5)2BrGeMn(CO)5, (C6H5)Br2GeMn(CO)5, Br3GeMn(CO)5 and Cl3GeMn(CO)5.
KeywordsSodium Manganese Carbonyl Halide Halogen
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