Phenylgermanium derivatives of manganese carbonyl

  • A. N. Nesmeyanov
  • K. N. Anisimov
  • N. E. Kolobova
  • A. B. Antonova
Brief Communications

Conclusions

  1. 1.

    As a result of the reactions of the sodium salt of manganese carbonyl with phenylgermanium halide derivatives, we produced bimetallic compounds: (C6H5)3GeMn(CO)5, (C6H5)2Ge[Mn(CO)5]2 and [(C6H5)2GeMn(CO5]2.

     
  2. 2.

    (C6H5)3GeMn(CO)4P(C6H5)3, (C6H5)3GeMn(CO)4As(C6H5)3 and (C6H5)3GeMn(CO)4Sb(C6H5)3 were produced by replacement of the CO groups in the bimetallic compounds by phosphines, arsines, and stibines.

     
  3. 3.

    Under the action of halogens on phenylgermanium derivatives of manganese carbonyl, we produced (C6H5)2BrGeMn(CO)5, (C6H5)Br2GeMn(CO)5, Br3GeMn(CO)5 and Cl3GeMn(CO)5.

     

Keywords

Sodium Manganese Carbonyl Halide Halogen 

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Literature cited

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    D. Seyferth, H. P. Hofmann, R. Burton and J. F. Helling, Inorgan. Chem.,1, 227 (1962).Google Scholar
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    W. Hieber and W. Freyer, Chem. Ber.,92, 1765 (1959).Google Scholar
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    J. G. Luijten and F. Rijkens, Recueil trav chem.,83, 857 (1964).Google Scholar
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    L. Bellamy, Infrared Spectra of Complex Molecules [Russian Translation], Moscow, 1963, p. 185.Google Scholar
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    N. A. Chumaevskii, Uspekhi Khimii,32, 1152 (1963).Google Scholar

Copyright information

© Consultants Bureau 1966

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • K. N. Anisimov
    • 1
  • N. E. Kolobova
    • 1
  • A. B. Antonova
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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