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Phenylgermanium derivatives of manganese carbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    As a result of the reactions of the sodium salt of manganese carbonyl with phenylgermanium halide derivatives, we produced bimetallic compounds: (C6H5)3GeMn(CO)5, (C6H5)2Ge[Mn(CO)5]2 and [(C6H5)2GeMn(CO5]2.

  2. 2.

    (C6H5)3GeMn(CO)4P(C6H5)3, (C6H5)3GeMn(CO)4As(C6H5)3 and (C6H5)3GeMn(CO)4Sb(C6H5)3 were produced by replacement of the CO groups in the bimetallic compounds by phosphines, arsines, and stibines.

  3. 3.

    Under the action of halogens on phenylgermanium derivatives of manganese carbonyl, we produced (C6H5)2BrGeMn(CO)5, (C6H5)Br2GeMn(CO)5, Br3GeMn(CO)5 and Cl3GeMn(CO)5.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova & A. B. Antonova

Authors
  1. A. N. Nesmeyanov
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  2. K. N. Anisimov
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  3. N. E. Kolobova
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  4. A. B. Antonova
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Additional information

We should like to thank Yu. N. Sheinker and G. G. Dvoryantseva for measuring the IR, spectra.

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Nesmeyanov, A.N., Anisimov, K.N., Kolobova, N.E. et al. Phenylgermanium derivatives of manganese carbonyl. Russ Chem Bull 15, 139–141 (1966). https://doi.org/10.1007/BF00845857

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  • DOI: https://doi.org/10.1007/BF00845857

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