Spectra and molecular structure of nitric acid in solutions Communication 2. Solutions of 1,2-dichloroethane, methylene chloride, and chloroform

  • A. P. Genich
  • L. T. Eremenko
  • L. A. Nikitina
Physical Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    The basic type of interaction of nitric acid with the solvents considered (1,2-dichloroethane, methylene chloride, and chloroform) is complex formation; the constants of complex formation were evaluated.

     
  2. 2.

    It was hypothesized that the bond in the acid-solvent complex is formed not at the nitro-group but at the acid proton.

     

Keywords

Methylene Chloride Chloroform Molecular Structure Nitric Acid 

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Literature cited

  1. 1.
    L. T. Eremenko and A. P. Genich, Izv. AN SSSR, Ser. khim.,1965, No. 12.Google Scholar
  2. 2.
    Mavel, Compt. rend,250, 3473 (1960).Google Scholar
  3. 3.
    R. N. Jones and G. D. Thorn, Canad. J. Research,27B, 580 (1950).Google Scholar

Copyright information

© Consultants Bureau 1966

Authors and Affiliations

  • A. P. Genich
    • 1
  • L. T. Eremenko
    • 1
  • L. A. Nikitina
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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