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Investigations in the field of metallochemistry Communication 6. Suboxides of the transition metals

  • I. I. Kornilov
  • V. V. Glazova
Inorganic and Analytical Chemistry

Conclusions

  1. 1.

    The solubility of oxygen in the transition metals depends upon the position of the element in the Periodic System; it is a maximum for metals with a great degree of incompletion of the d-electron shell and decreases as it is filled.

     
  2. 2.

    When a definite critical concentration of oxygen in the solid solutions formed has been reached, there is a very slow formation of suboxides with an ordered structure and an individual type of crystal lattice. The formation of suboxides is possible according to a peritectoid reaction.

     
  3. 3.

    The existence of two suboxide compounds of titanium has been detected (Ti6O and Ti3O); the existence of a series of suboxides in the transition metal-oxygen systems has been hypothesized.

     

Keywords

Oxygen Titanium Solid Solution Crystal Lattice Great Degree 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1966

Authors and Affiliations

  • I. I. Kornilov
    • 1
  • V. V. Glazova
    • 1
  1. 1.A. A. Baikov Institute of MetallurgyUSSR

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