Investigations in the field of metallochemistry Communication 6. Suboxides of the transition metals

  • I. I. Kornilov
  • V. V. Glazova
Inorganic and Analytical Chemistry


  1. 1.

    The solubility of oxygen in the transition metals depends upon the position of the element in the Periodic System; it is a maximum for metals with a great degree of incompletion of the d-electron shell and decreases as it is filled.

  2. 2.

    When a definite critical concentration of oxygen in the solid solutions formed has been reached, there is a very slow formation of suboxides with an ordered structure and an individual type of crystal lattice. The formation of suboxides is possible according to a peritectoid reaction.

  3. 3.

    The existence of two suboxide compounds of titanium has been detected (Ti6O and Ti3O); the existence of a series of suboxides in the transition metal-oxygen systems has been hypothesized.



Oxygen Titanium Solid Solution Crystal Lattice Great Degree 
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Copyright information

© Consultants Bureau 1966

Authors and Affiliations

  • I. I. Kornilov
    • 1
  • V. V. Glazova
    • 1
  1. 1.A. A. Baikov Institute of MetallurgyUSSR

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