Summary
A method has been developed for the synthesis of cyclopentadienyltricarbonyl and methylcyclopentadienyl-tricarbonyl manganese by the reaction of cyclopentadienyl and methylcyclopentadienyl sodium with chloro (bromo)-pentacarbonyl manganese in tetrahydrofuran medium.
Literature cited
A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and L. I. Baryshnikov, Izv. AN SSSR, Otd. khim. n., 1963, 193.
U.S. Patent 3015668 (1962).
H. E. Podall, I. H. Dunn, and H. Shapiro, J. Amer. Chem. Soc.,82, 1325 (1960).
E. W. Abel and G. Wilkinson, I. Chem. Soc., 1959, 1501.
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Nesmeyanov, A.N., Anisimov, K.N. & Kolobova, N.E. Synthesis of cyclopentadienyl and methylcyclopentadienyltricarbonyl manganese. Russ Chem Bull 12, 1734–1735 (1963). https://doi.org/10.1007/BF00845819
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DOI: https://doi.org/10.1007/BF00845819