The effect of the polarity of the oxidized substrate on the inhibiting activity of compounds with a conjugation system
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The inhibiting activity of compounds with a conjugation system (anthracene, polyphenylene, polyphenylacetylene) in thermal oxidation increases in agreement with the increase in polarity of the oxidized substrate, i.e., in the order ceresin <dioctyl phthalate<dibutyl phthalate < diethyl phthalate.
The results obtained confirm the proposed mechanism for the inhibiting action of compounds with a conjugation system that are activated by paramagnetic centers of local activation present in them.
KeywordsOxidation Inhibiting Activity Diethyl Anthracene Phthalate
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- 1.S. I. Bass, A. M. Zil'berbrandt, and A. A. Berlin, Zh. fiz. khimii, No. 3 (1963).Google Scholar
- 2.A. A. Berlin and S. I. Bass, Dokl. AN SSSR, 1963 (in press).Google Scholar
- 3.A. A. Berlin and S. I. Bass, Izv. AN SSSR, Otd. khim. n., 1962, 1492.Google Scholar
- 4.A. A. Berlin, Khim. prom-st' No. 12, 881 (1962).Google Scholar
- 5.A. A. Berlin and S. I. Bass, Izv. AN SSSR, Otd. khim. n. 1963 (in press).Google Scholar