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Catalytic reaction of trialkyl(aryl)silanes with allyl alcohol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study has been made of the catalytic reaction between trialkyl(aryl)silanes and allyl alcohol in the presence of small additions of alkali metals or of zinc and tin halides.

  2. 2.

    A convenient method has been developed for preparing 3-trialkyl(aryl)siloxypropenes-1 through trialkyl(aryl)silanes, with a yield up to 80% of the theoretical.

  3. 3.

    Confirmation has been obtained for the regularities found earlier in the effect of trialkyl (aryl)silane radicals and the nature of the catalyst on the reaction rate.

  4. 4.

    Eleven trialkyl(aryl)allyloxysilanes have been synthesized for the first time.

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Literature cited

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences, USSR

    N. P. Kharitonov, G. T. Konstantinova, Yu. I. Khudobin & V. A. Komarov

Authors
  1. N. P. Kharitonov
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  2. G. T. Konstantinova
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  3. Yu. I. Khudobin
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  4. V. A. Komarov
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Kharitonov, N.P., Konstantinova, G.T., Khudobin, Y.I. et al. Catalytic reaction of trialkyl(aryl)silanes with allyl alcohol. Russ Chem Bull 12, 1606–1612 (1963). https://doi.org/10.1007/BF00845787

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  • DOI: https://doi.org/10.1007/BF00845787

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