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Inhibitor efficiency of tri-(3,5-ditert butyl-4-oxy)benzylamine as found from the critical concentration in n-decane oxidation

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A measurement has been made of the critical concentration of tri-(3,5-ditert. butyl-4-oxy)benzylamine inhibitor in n-decane oxidation in an open system.

  2. 2.

    The ratio has been found of the elementary rate constants for chain rupture at the inhibitor and the chain continuation rate, ki/k2=7.3·105.

  3. 3.

    The efficiency of tri-(3,5-ditert. butyl-4-oxy)benzylamine as an inhibitor in n-decane oxidation is almost a factor of 2 less than that of α-naphthol.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    A. B. Gagarina

Authors
  1. A. B. Gagarina
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Gagarina, A.B. Inhibitor efficiency of tri-(3,5-ditert butyl-4-oxy)benzylamine as found from the critical concentration in n-decane oxidation. Russ Chem Bull 12, 1586–1588 (1963). https://doi.org/10.1007/BF00845783

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  • DOI: https://doi.org/10.1007/BF00845783

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